| Atmospheric temperature* | 1 - primary | Cloud sensitive. | MWIR and TIR spectrometry in the CO2  4.3 and 15 micrometer bands.  Frequent sampling (GEO) enables monitoring instability onset | 
	| C2H2 | 3 - high | Cloud sensitive.. Coarse vertical resolution. | TIR spectrometry.  C2H2 lines around 7.5 and 13.7 micrometers.  Frequent sampling (GEO) enables monitoring diurnal variations | 
	| C2H6 | 3 - high | Cloud sensitive.. Coarse vertical resolution. | TIR spectrometry.  C2H6 lines around 12 micrometers.  Frequent sampling (GEO) enables monitoring diurnal variations | 
	| CFC-11 | 3 - high | Cloud sensitive.. Coarse vertical resolution. | TIR spectrometry.  CFC-11 lines around 9.2 and 11.7 micrometers. Frequent sampling (GEO) enables monitoring diurnal variations | 
	| CFC-12 | 3 - high | Cloud sensitive.. Coarse vertical resolution. | TIR spectrometry.  CFC-12 lines around 8.8 and 10.8  micrometers.  Frequent sampling (GEO) enables monitoring diurnal variations | 
	| CH4 mole fraction | 2 - very high | Cloud sensitive.. Coarse vertical resolution. | MWIR and TIR spectrometry.  CH4 lines around 4.3 and 7.7 micrometers.  Frequent sampling (GEO) enables monitoring diurnal variations | 
	| ClONO2 | 2 - very high | Cloud sensitive.. Coarse vertical resolution. | MWIR and TIR spectrometry.  ClONO2 lines around 5.7, 7.7 and 12.5 micrometers.  Frequent sampling (GEO) enables monitoring diurnal variations | 
	| Cloud cover | 3 - high | Discontinuous coverage. | MWIR and TIR spectrometry | 
	| Cloud top height | 2 - very high | Discontinuous coverage. | MWIR and TIR spectrometry in window and water vapour band (for emissivity) to estimate cloud top height from its temperature | 
	| Cloud top temperature | 1 - primary | Discontinuous coverage. | TIR spectrometry in window and water vapour band (for emissivity) | 
	| Cloud type | 4 - fair | Discontinuous coverage. | MWIR and TIR spectrometry | 
	| CO | 3 - high | Cloud sensitive.. Coarse vertical resolution. | MWIR spectrometry.  CO lines around 4.6.  Frequent sampling (GEO) enables monitoring diurnal variations | 
	| CO2 mole fraction | 3 - high | Cloud sensitive.. Coarse vertical resolution. | TIR spectrometry.  CO2 lines around 15 micrometers.  Frequent sampling (GEO) enables monitoring diurnal variations | 
	| COS | 3 - high | Cloud sensitive.. Coarse vertical resolution. | TIR spectrometry.  COS lines around 11.6 micrometers.  Frequent sampling (GEO) enables monitoring diurnal variations | 
	| Downward long-wave irradiance at Earth surface | 1 - primary | Cloud sensitive.. Highly indirect. | MWIR and TIR spectrometry including water vapour and CO2 bands | 
	| H2O | 2 - very high | Cloud sensitive.. Coarse vertical resolution. | MWIR/TIR spectrometry in a range centred on 6.3 micrometers.  Frequent sampling (GEO) enables monitoring diurnal variations | 
	| Height of the top of PBL | 4 - fair | Cloud sensitive. | MWIR and TIR spectrometry.  Height of PBL top from temperature profile.  Frequent sampling (GEO) enables monitoring the PBL evolution | 
	| Height of the tropopause | 4 - fair | Cloud sensitive. | TIR spectrometry.  Height of tropopause from temperature profile.  Frequent sampling (GEO) enables monitoring the tropopause evolution | 
	| HNO3 | 3 - high | Cloud sensitive.. Coarse vertical resolution. | MWIR and TIR spectrometry.  HNO3 lines around 5.9, 7.6 and 11.3 micrometers.  Frequent sampling (GEO) enables monitoring diurnal variations | 
	| Land surface temperature | 2 - very high | Cloud sensitive.. Coarse spatial resolution. | MWIR and TIR spectrometry (inclusive of several narrow-bandwidth windows and absorption bands for atmospheric corrections) | 
	| Long-wave Earth surface emissivity | 1 - primary | Cloud sensitive.. Long time series needed. | MWIR and TIR spectrometry measuring land temperature in many windows.  Emissivity inferred by statistical analysis | 
	| N2O mole fraction | 2 - very high | Cloud sensitive.. Coarse vertical resolution. | MWIR and TIR spectrometry.  N2O lines around 4.5 and 7.7 micrometers.  Frequent sampling (GEO) enables monitoring diurnal variations | 
	| N2O5 | 3 - high | Cloud sensitive.. Coarse vertical resolution. | MWIR and TIR spectrometry.  N2O5 lines around 5.8 and 8 micrometers.  Frequent sampling (GEO) enables monitoring diurnal variations | 
	| NO | 3 - high | Cloud sensitive.. Coarse vertical resolution. | MWIR spectrometry.  NO lines around 5.3 micrometers.  Frequent sampling (GEO) enables monitoring diurnal variations | 
	| NO2 | 3 - high | Cloud sensitive.. Coarse vertical resolution. | TIR spectrometry.  NO2 lines around 6.1 micrometers.  Frequent sampling (GEO) enables monitoring diurnal variations | 
	| NO2  Total Column | 4 - fair | Cloud sensitive. | TIR spectrometry.  NO2 lines around 6.1 micrometers.  Frequent sampling (GEO) enables monitoring diurnal variations | 
	| O3 | 3 - high | Cloud sensitive.. Coarse vertical resolution. | TIR spectrometry.  Ozone band around 9.7 micrometers. Frequent sampling (GEO) enables monitoring diurnal variations | 
	| O3 Total Column | 3 - high | Cloud sensitive. | TIR channel(s).  Ozone lines in band around 9.7 micrometers.  Frequent sampling (GEO) enables monitoring diurnal variations | 
	| PAN | 3 - high | Cloud sensitive.. Coarse spatial resolution. | MWIR and TIR spectrometry.  PAN lines around 5.7, 8.6 and 12.5 micrometers.  Frequent sampling (GEO) enables monitoring diurnal variations | 
	| PSC occurrence | 2 - very high | Marginal view from GEO.. Coarse vertical resolution. | MWIR and TIR spectroscopy | 
	| Sea surface temperature | 1 - primary | Cloud sensitive. | MWIR and TIR spectrometry (inclusive of several narrow-bandwidth windows and absorption bands for atmospheric corrections) | 
	| SF6 | 3 - high | Cloud sensitive.. Coarse vertical resolution. | TIR spectrometry.  SF6 lines around 10.5  micrometers.  Frequent sampling (GEO) for diurnal variations | 
	| SO2 | 2 - very high | Cloud sensitive.. Coarse vertical resolution. | TIR spectrometry.  SO2 lines around 7.3 and 8.6 micrometers.  Frequent sampling (GEO) for sources monitoring | 
	| SO2 Total Column | 2 - very high | Cloud sensitive. | TIR spectrometry.  SO2 lines around 7.3 and 8.6 micrometers.  Frequent sampling (GEO) for sources monitoring | 
	| Specific humidity* | 1 - primary | Cloud sensitive. | TIR spectrometry in the water vapour band around 6.3 micrometers.  Frequent sampling (GEO) enables monitoring instability onset | 
	| Integrated Water Vapour (IWV)* | 2 - very high | Cloud sensitive. | TIR spectrometry in the bands around 6.3 and above 11 micrometers.  Frequent sampling (GEO) enables monitoring instability onset | 
	| Temperature of the tropopause | 3 - high | Cloud sensitive. | TIR spectrometry.  Tropopause temperature from temperature profile.  Frequent sampling (GEO) enables monitoring the tropopause evolution | 
	| Upward spectral radiance at TOA | 2 - very high | Missing all Short-waves. | MWIR and TIR spectrometry resolving water vapour lines in the bands around 6.3 micrometers and 11 to 15 micrometers; and other greenhouse gases | 
	| Upward long-wave irradiance at TOA | 3 - high | Spectral interpolation needed. | MWIR and TIR spectrometry in the windows regions around 3.7 and 11 micrometers, and in water vapour and CO2 bands around 4,3, 6.3 and 15 micrometers | 
	| Upward long-wave irradiance at Earth surface | 1 - primary | Cloud sensitive.. Highly indirect. | MWIR and TIR channels in windows around 3.7 and 11 micrometers, and in water vapour and CO2 bands around 4,3, 6.3 and 15 micrometers | 
	| Wind (horizontal) | 2 - very high | Cloud sensitive.. Water vapour tracers needed. | TIR spectrometry in the 6.3 micrometers band.  Wind profile in clear air by tracking water vapour patches in the humidity profile |